Rediscovering fire with a little stick
From striking stones against each other to lighting a matchstick, humans have come a long way when it comes to igniting fire. The first matchstick was invented accidentally by John Walker, an English chemist. Walker was stunned when a chemical coating stick burst into flames after contact with his stone fireplace. After this, he created a first prototype of the modern matchstick. Initially named ‘friction lights’, it became a trend in the market. However, Walker did not patent his invention. Samuel Jones launched matchsticks and called them ‘Lucifers’. They burst into unpredictable flames, emitting a peculiar smell. The tips of these matches contained a coating of antimony sulphide, potassium chlorate, starch and gum. These sticks could be ignited when stroked between folded sandpaper. The credit for creating noiseless matchsticks goes to Janos Irinyi, a student, in 1835. He replaced potassium chlorate with lead dioxide. This resulted in the sticks burning evenly throughout. Eventually, the safety matches we see today were invented by Swedish inventor and professor Gustaf Erik Pasch in 1844. After a decade, John Edvard Lundstrom improvised on the design.
Ever wondered how a matchstick lights up with a single spark? The head of the match consists of antimony trisulfide, which acts as the fuel. Potassium chlorate aids in the fuel burning, leading to ignition of the matchstick. Whereas ammonium phosphate plays the other role, preventing the matchstick from emitting too much smoke after being extinguished. When you light a match, the flame travels downwards. This is due to the wax present on the matchstick. Glue holds all this together. The dye makes the matchstick look more presentable! Powdered glass is present on the striking surface, for friction, whereas red phosphorus ignites the flame. When you strike the match against the powdered glass, it creates friction, which leads to heat, and this converts red phosphorus to white phosphorus. White phosphorus is extremely volatile, and reacts with oxygen in the air. This results in the matchstick igniting. The flame that you see in the matchstick is due to heat which ignites the potassium chlorate. Potassium chlorate is an oxidiser, aiding in burning of the fuel by supplying more oxygen. This oxygen in turn mixes with antimony trisulfide, ensuring that the flame lasts longer. Paraffin wax is coated along the matchstick, ensuring that the flame travels all down the match, across the wooden stick. After the matchstick is extinguished, a familiar burnt scent is released. This occurs as the antimony oxidises and sulphur oxides form. The smoke that emanates is from tiny unburnt particles, from the incomplete combustion process. Usually, these particles are very minute, but when grouped together, they form smoke. A little amount of water vapour is also present.
Matchboxes were perfected over time by Lundstrom and his younger brother Carl. Boxes were created as per the size and use of the matchsticks. Until 1830, the matchsticks were known as Lucifer matches. However, cigarette lighters were invented in 1816, much before matches were invented. Today, around the world, about half a trillion matches are used each year.
